The central reason to investigate RO4835 alongside RO4350B is long-term behavior in an oxidative thermal environment. Similar initial electrical data do not answer whether a specific circuit remains within its limits over its intended service life.

Define the exposure before comparing

Record continuous and peak temperatures, dwell times, oxygen exposure, protective coating and the amount of exposed dielectric in the layout. Material aging depends on the physical circuit and environment. An enclosure temperature alone may not describe the temperature near a power device. Do not turn a manufacturer comparison into an unconditional lifetime multiplier for a completed PCB.

Separate initial performance from drift

Compare RO4350B and RO4835 at equivalent thickness and copper configuration. Rogers positions RO4835 for improved oxidation resistance, but the initial impedance, loss and phase still require a valid model. A candidate that reduces aging concerns can still require dimensional or assembly changes. Preserve the exact source revisions used for the decision.

Example: an outdoor RF module

Consider a module whose narrowband response has little room for frequency drift. Build a baseline sample and candidate sample, measure the initial response, and expose them to an engineering-approved aging condition. Repeat measurements using the same temperature and recovery procedure. Compare resonance or phase drift, insertion loss and physical condition. This is a proposed evaluation approach; the site has not performed an aging test on either material.

Make qualification relevant to service

An accelerated test should have a defensible relationship to the failure mechanism you are investigating. A convenient oven exposure is not automatically a lifetime prediction. Agree acceptance limits and sample selection before testing, and include the bonding system, coating and finish used in production. Review the qualification workflow and seek material-specific guidance where the expected environment falls outside available evidence. If ordinary conditions already meet the requirement, a material change needs a clear benefit to justify requalification.

Inspect the places where dielectric is exposed around patterned copper and board edges when defining the aging sample. A fully clad reference coupon and an etched RF structure can present different exposure conditions, so choose the vehicle for the failure mechanism being investigated.

Source-aware property comparison

RO4350B

RO4350B — reported properties and conditions
PropertyReported valueConditions / source
Process dielectric constant3.48 ± 0.05Typical, 10 GHz, 23°C; IPC-TM-650 2.5.5.5 clamped stripline; thickness direction. Source
Design dielectric constant3.66Typical, 8–40 GHz; differential phase length method. Average across the common constructions in the cited datasheet. Source
Dissipation factor0.0037Typical, 10 GHz, 23°C; IPC-TM-650 2.5.5.5; thickness direction. Source
Thermal conductivity0.69 W/(m·K)Typical; ASTM C518, 80°C; through-thickness thermal conduction. Source
CTE, X axis10 ppm/°CTypical; -55°C to 288°C, IPC-TM-650 2.4.41; average expansion over the interval, not necessarily linear. Source
CTE, Y axis12 ppm/°CTypical; -55°C to 288°C, IPC-TM-650 2.4.41; average expansion over the interval, not necessarily linear. Source
CTE, Z axis32 ppm/°CTypical; -55°C to 288°C, IPC-TM-650 2.4.41; average expansion over the interval, not necessarily linear. Source
Thermal coefficient of dielectric constant50 ppm/°CTypical; -50°C to 150°C, IPC-TM-650 2.5.5.5 (modified temperature measurement); 10 GHz. Source
Water absorption0.06 %Typical; 48 h at 50°C, 60 mil specimen, ASTM D570. Source
Density1.86 g/cm³Typical; 23°C, ASTM D792. Source

Typical reported values are not a purchase specification. Process Dk, design Dk and values measured at different frequencies are not interchangeable.

RO4835

RO4835 — reported properties and conditions
PropertyReported valueConditions / source
Process dielectric constant3.48 ± 0.05Typical, 10 GHz, 23°C; IPC-TM-650 2.5.5.5 clamped stripline; thickness direction. Source
Design dielectric constant3.66Typical, 8–40 GHz; differential phase length method. Average across the common constructions in the cited datasheet. Source
Dissipation factor0.0037Typical, 10 GHz, 23°C; IPC-TM-650 2.5.5.5; thickness direction. Source
Thermal conductivity0.66 W/(m·K)Typical; ASTM C518, 80°C; through-thickness thermal conduction. Source

Typical reported values are not a purchase specification. Process Dk, design Dk and values measured at different frequencies are not interchangeable.

Evaluate RO4835 for a defined aging risk and validate drift on the actual circuit construction.

Technical sources